Minerals and Rocks

To appreciate the geology of California we must understand minerals and rocks. Harden does not go too much into minerals.

All minerals are made of chemical elements. So let�s look into this.

Chemical Element: the most fundamental substance into which matter can be separated by chemical means.

You should know the name and chemical symbols of the most abundant elements in the Earth�s crust.


Oxygen O 45%
Silicon Si 27%
Aluminum Al 8%
Iron Fe 6%
Calcium Ca 5%
Magnesium Mg 3%
Sodium Na 2%
Potassium K 2%

Other elements to know are fluorine (F), Chlorine (Cl), sulfer (S), and carbon (C).

Let�s review the structure elements.

Atom: the smallest individual particle that retains all of the properties of a given chemical element.



Most simple model for an atom. http://instruct.westvalley.edu/lopez/geo_1b/images/simple_atom.jpg

In an electrostatically balanced atom, the number of electrons equals the number of protons. For example, oxygen (O) has eight protons, eight electrons, and usually eight neutrons (we will discuss isotopes when we talk about absolute dating techniques and Geologic Time).

However, the atom may gain or lose electrons. When this happens, the atom is no longer balanced and becomes an ION.


ION
: unbalanced atom, could be (+) or (-).
Cation
: atom loses an electron and becomes positively charged.
Anion
: atom gains an electron and becomes negatively charged.
NaCl ionic bonding - Chemical Compound. http://instruct.westvalley.edu/lopez/geo_1b/images/na_cl-ions.jpg

 

Chemical Compound: a substance composed of more than one element.

For example, common table salt is the chemical compound sodium chloride, NaCl.

Minerals: the basic building blocks of rocks, i.e. all rocks are composed of minerals. Some rocks may be formed of just one mineral, but most are composed of several, average of 5 to 10.

3000 recognized minerals, we will learn about 10 to 15 (the common rock forming minerals).

Definition of a Mineral:

  1. is naturally occurring. Glacial ice is a mineral, refrigerator ice is not.
  2. Is solid (not gas or liquid).
  3. Has a specific chemical composition, i.e. the composition is either fixed or varies very little.
  4. Has a characteristic crystalline structure (internal arrangement of atoms), which result in specific chemical properties.

A mineral can be composed of a single element.

Graphite, C. Pencil "lead" is graphite, very soft.

Can anyone think of another mineral composed entirely of carbon?

Diamond�the hardest of all minerals. These two minerals have the same chemical composition, but very different physical properties.

Polymorphs�same chemical composition, but different internal arrangement of atoms and different physical properties.

 

Mineral Composition Chemical Compound

Halite NaCl sodium chloride

Quartz SiO2 Silicon dioxide

Calcite CaCO3 calcium carbonate

These minerals are examples of minerals with fixed chemical compositions.

They basically have the same composition where ever you find them.

Feldspar: is just about everywhere and is an example of a mineral whose composition can vary.

Two types of feldspar K-feldspar and Plagioclase

Plagioclase feldspar varies in composition by its content of Na, Ca, Al, and Si.

NaAlSi3O8------CaAl2Si2O8

Caà Na substitution

Alà Si substitution

Plagioclase can vary in composition from rock to rock, but its composition is constant in any single rock.

 

Crystalline Structure: the atoms of ions in a mineral are arranged in a specific 3-dimensional pattern. Each mineral has its own unique pattern or internal arrangement of atoms or ions.

This is how glass differs from crystalline material.

Glass is AMORPHOUS, no crystalline structure.

Now let�s discuss the physical properties of minerals.

PHYSICAL PROPERTIES

  1. Crystal Form
  2. Cleavage and/or Fracture
  3. Hardness
  4. Color
  5. Luster
  6. Specific Gravity
  1. Crystal Form: is produced during natural, unperturbed growth, which leads to a characteristic crystal form, e.g. QUARTZ. The crystal form reflects the internal structure of the mineral. No matter what size the crystal is (few millimeter to ten�s of centimeters), QUARTZ crystals will have HEXAGONAL, SIX SIDED PRISMS.
  2. Cleavage/Fracture: CLEAVAGE is the tendency of a mineral to break in certain preferred directions. The breaks produce a smooth, shiny face. They may look like crystal faces, but they are not. Cleavage is characterized in three ways. (A) Number of cleavage directions; (B) Angle between different cleavage directions; (C) Quality of Cleavage. Halite has 3 directions of cleavage at 90� to each other. Calcite has 3 directions of cleavage not at 90� to each other. Mica has 1 direction or planar cleavage Some minerals have no cleavage and break in a FRACTURE. A common fracture is Conchoidal Fracture, typical of Quartz and Olivine, which have no cleavage surfaces.
  3. Hardness�is one the most important properties used to identify minerals. Mohs Hardness Scale
  1. Talc�very soft, used in baby powder.
  2. Gypsum�plaster of Paris, for cement (FINGER NAIL = 2.5)
  3. Calcite�CaCo3, for cement use lime CaO
  4. Fluorite�CaF2
  5. Apatite�Ca5(PO4)(OH)�Bones and Teeth (KNIFE BLADE = 5.5)
  6. Feldspar�Very common, hard to scratch with knife
  7. Quartz�Also common, SiO2
  8. Topaz�Usually a gem,
  9. Corundum�Al2O3, Saphire, Ruby
  10. Diamond, Carbon, hardest

  1. Color: Not as reliable, but used to distinguish minerals with higher concentrations of Fe and Mg.
  2. Luster�The way the mineral reflects light. Metallic and Non-Metallic Non-metallic�VITREOUS (glassy, shiny like quartz and micas) ADAMANTINE (Brilliant like Diamond) Dull (earthy; like kaolinite)
  3. Pearly (like talk)

    Waxy (like jasper)

    Resinous (like sphalerite)

  4. Specific Gravity�weight of the mineral compared to an equal volume of water (no units). QUARTZ = 2.7; GOLD = 19.3

 

Special Properties are used to identify minerals

Effervescence�Calcite reacts with HCL to form CaO and CO3 gas.

Tenacity � toughness, describes the minerals resistance to being broken. [Adjectives � flexible (mineral is easily bent), elastic (mineral rebounds), brittle (mineral fractures into many pieces), malleable (mineral is bend like soft metal), sectile (mineral can be cut by knife)]

Magnetism � attraction to a magnet (Magnetite is most common)

Taste, Odor, Feel � Some minerals have a distinctive taste (halite � rock salt), some a distinctive odor (powder of sulfide minerals like sphalerite smells like rotten eggs), and some a distinctive feel (talc feels slippery, greasy).

Striations and Exsolution Lamellae

Striations are very thin, parallel grooves on some mineral faces � most commonly Plagioclase feldspar, some pyroxenes, tourmaline, and pyrite. Key thing is that these are physical grooves in mineral.

Exsolution Lamellae are thin veinlets seen mainly in Potassium Feldspar. These have variable widths and are not physical grooves. They are also not parallel.

 

Introduction to Igneous Rocks

Rocks we will see in the class exercise are Basalt (14), Andesite (14), Dacite (4), Rhyolite (9), Obsidian (18), Volcanic Tuff (8), Pumice (12), Pegmatitic, large grain granite (25), course grained granite-Diorite (15), Diroite-Gabbro (20), and Gabbro (40).

Igneous rock: forms by the cooling and solidification of magma.

Magma: molten rock, which may include suspended minerals and dissolved gasses.

Two types of Igneous rock. Extrusive and Intrusive

Extrusive: lava, pryoclastic material, magma coming out of a volcano.

Intrusive: magma solidifies within the Earth�s crust or mantle.

 

Classification of Igneous Rocks.

Igneous rocks: classified based on Rock Texture and Mineral Assemblage.

Rock Texture

Size of mineral grains�Intrusive rocks tend to be coarse grained because minerals grow slowly in the Earth�s crust or mantle. Extrusive rocks tend to be fine grained to glassy because they cool rapidly on the surface of the Earth.

Textural terms

Phaneritic�the minerals are visible to the eye.

Aphanitic�the minerals are not visible to the eye.

Porphyritic�When on mineral is considerably courser, larger than the other minerals. Often the groundmass or matrix is fine grained.

Pegmatitic�Pegmatite, when all minerals are enormous, i.e. big.

Glassy�basically aphanitic, but typical of volcanic glass, obsidian.

Mineral Assemblage

Phenocryst�Minerals in rocks are termed phenocrysts.

These consist of the Major Rock Forming Minerals.

Quartz

Feldspar (K-spar and plagioclase)

Mica (Biotite and Muscovite)

Amphibole (hornblende)

Pyroxene

Olivine

Depending on what minerals you have in the rock, classifies or names the rock.

See Handout on igneous rocks.

Basically, Quartz is typical of rocks like Granite and Rhyolite, where as olivine is typical of rocks like basalt and Gabbro.

Note that rocks become darker in color as more of the darker minerals are present in the rock. We call this the COLOR INDEX. Granites have a CI of 25 or less. Basalts have a CI of 90 to 100.